Lithium, sodium, and potassium magnesiate chemistry : a structural overview

Until recently, deprotonative metalation reactions have been performed using organometallic compounds that contain only a single metal (eg, organolithium reagents). Since the turn of the millennium, bimetallic compounds such as alkali metal magnesiates have begun to emerge as a new class of complementary metalating reagents. These have many benefits over traditional lithium compounds, including their enhanced stability at ambient temperatures, their tolerance of reactive functional groups and their stability in common reaction solvents. In recent years, lots of attention has been focused on understanding the structure of alkali metal magnesiates in an effort to maximize synthetic efficiency and thus shed insight into approaches for future rational design. In this chapter, the diverse structural chemistry of alkali metal magnesiate compounds reported since 2007 will be summarized

Topological and spectral properties of random digraphs

We investigate some topological and spectral properties of Erd\H{o}s-R\'{e}nyi (ER) random digraphs $D(n,p)$. In terms of topological properties, our primary focus lies in analyzing the number of non-isolated vertices $V_x(D)$ as well as two vertex-degree-based topological indices: the Randi\'c index $R(D)$ and sum-connectivity index $\chi(D)$. First, by performing a scaling analysis we show that the average degree $\langle k \rangle$ serves as scaling parameter for the average values of $V_x(D)$, $R(D)$ and $\chi(D)$. Then, we also state expressions relating the number of arcs, spectral radius, and closed walks of length 2 to $(n,p)$, the parameters of ER random digraphs. Concerning spectral properties, we compute six different graph energies on $D(n,p)$. We start by validating $\langle k \rangle$ as the scaling parameter of the graph energies. Additionally, we reformulate a set of bounds previously reported in the literature for these energies as a function $(n,p)$. Finally, we phenomenologically state relations between energies that allow us to extend previously known bounds

Chemical weathering of the volcanic soils of Isla Santa Cruz (Galápagos Islands, Ecuador)

We present a study on weathering of volcanic soils using 43 profiles (131 horizons) sampled in Santa Cruz Island (Galapagos Islands). Several weathering indices, based on chemical composition, are used. Since the geological material is highly homogeneous the intensity of weathering is mostly related to climatic conditions controlled by topography. There is a gradient of increasing weathering from the arid conditions predominant in the coast to elevations of 400-500 m a.s.l. where much more humid conditions prevail

Pointwise convergence of vector-valued Fourier series

We prove a vector-valued version of Carleson's theorem: Let Y=[X,H]_t be a complex interpolation space between a UMD space X and a Hilbert space H. For p\in(1,\infty) and f\in L^p(T;Y), the partial sums of the Fourier series of f converge to f pointwise almost everywhere. Apparently, all known examples of UMD spaces are of this intermediate form Y=[X,H]_t. In particular, we answer affirmatively a question of Rubio de Francia on the pointwise convergence of Fourier series of Schatten class valued functions.Comment: 26 page

The evolution of the Sun's birth cluster and the search for the solar siblings with Gaia

We use self-consistent numerical simulations of the evolution and disruption of the Sun's birth cluster in the Milky Way potential to investigate the present-day phase space distribution of the Sun's siblings. The simulations include the gravitational N-body forces within the cluster and the effects of stellar evolution on the cluster population. In addition the gravitational forces due to the Milky Way potential are accounted for in a self-consistent manner. Our aim is to understand how the astrometric and radial velocity data from the Gaia mission can be used to pre-select solar sibling candidates. We vary the initial conditions of the Sun's birth cluster, as well as the parameters of the Galactic potential. We show that the disruption time-scales of the cluster are insensitive to the details of the non-axisymmetric components of the Milky Way model and we make predictions, averaged over the different simulated possibilities, about the number of solar siblings that should appear in surveys such as Gaia or GALAH. We find a large variety of present-day phase space distributions of solar siblings, which depend on the cluster initial conditions and the Milky Way model parameters. We show that nevertheless robust predictions can be made about the location of the solar siblings in the space of parallaxes ($\varpi$), proper motions ($\mu$) and radial velocities ($V_\mathrm{r}$). By calculating the ratio of the number of simulated solar siblings to that of the number of stars in a model Galactic disk, we find that this ratio is above 0.5 in the region given by: $\varpi \geq 5$mas, $4 \leq \mu \leq 6$masyr$^{-1}$, and $-2\leq V_\mathrm{r} \leq 0$kms$^{-1}$. Selecting stars from this region should increase the probability of success in identifying solar siblings through follow up observations [Abridged].Comment: 13 pages, 7 figures. Accepted for publication in MNRA

Supernova Inelastic Neutrino-Nucleus Cross Sections from High-Resolution Electron Scattering Experiments and Shell-Model Calculations

Highly precise data on the magnetic dipole strength distributions from the Darmstadt electron linear accelerator for the nuclei 50Ti, 52Cr and 54Fe are dominated by isovector Gamow-Teller-like contributions and can therefore be translated into inelastic total and differential neutral-current neutrino-nucleus cross sections at supernova neutrino energies. The results agree well with large-scale shell-model calculations, validating this model.Comment: 5 pages, 4 figures, RevTeX 4, version accepted in Phys. Rev. Letter

Superscaling Predictions for Neutral Current Quasielastic Neutrino-Nucleus Scattering

The application of superscaling ideas to predict neutral-current (NC) quasielastic (QE) neutrino cross sections is investigated. Results obtained within the relativistic impulse approximation (RIA) using the same relativistic mean field potential (RMF) for both initial and final nucleons -- a model that reproduces the experimental (e,e') scaling function -- are used to illustrate the ideas involved. While NC reactions are not so well suited for scaling analyses, to a large extent the RIA-RMF predictions do exhibit superscaling. Independence of the scaled response on the nuclear species is very well fulfilled. The RIA-RMF NC superscaling function is in good agreement with the experimental (e,e') one. The idea that electroweak processes can be described with a universal scaling function, provided that mild restrictions on the kinematics are assumed, is shown to be valid.Comment: 4 pages, 4 figures, published in PR